Scorpionates : The Coordination Chemistry of Polypyrazolylborate Ligands


Swiatoslaw. Trofimenko
Bok Engelsk 1999 · Electronic books.
Annen tittel
Utgitt
Singapore : : World Scientific Publishing Company, , 1999.
Omfang
1 online resource (294 p.)
Opplysninger
Description based upon print version of record.. - Preface; Contents; Chapter 1 Introduction; 1.1 General Considerations; 1.2 Polypyrazolylborates - Scorpionates; 1.3 The Abbreviation System for Scorpionate Ligands; 1.4 Comparison of the Tp and Cp Ligands; 1.5 Historical Development; 1.6 Reviews; 1.7 Synthesis of Scorpionate Ligands; 1.7.1 Bpx Ligands; 1.7.2 Tpx Ligands; 1.7.3 pzoTpx Ligands; 1.7.4 Ligands Containing C-B Bonds; 1.7.4.1 R2Bpx ligands; 1.7.4.2 RB(pzx)3 ligands; 1.8 List of Known Scorpionate Ligands; 1.9 Analogs of Scorpionate Ligands; 1.9.1 Replacement of Pyrazole; 1.9.2 Replacement of Boron; 1.9.2.1 Aluminum and Indium. - 1.9.2.2 Gallium1.9.2.3 Carbon; 1.9.2.4 Silicon; 1.9.2.5 Other elements; Chapter 2 Homoscorpionates - First Generation; 2.1 General Considerations; 2.2 Group 1: H, Li, Na, K, Rb and Cs; 2.2.1 H; 2.2.2 Li, Na, K, Rb and Cs; 2.3 Group 2: Be, Mg, Ca, Sr, Ba; 2.3.1 Be; 2.3.2 Mg; 2.3.3 Ca, Sr, Ba; 2.4 Group 3: Sc, Y (lanthanides and actinides are listed separately); 2.4.1 Sc; 2.4.2 Y; 2.5 Group 4: Ti, Zr, Hf; 2.5.1 Ti; 2.5.2 Zr; 2.5.3 Hf; 2.6 Group 5: V, Nb, Ta; 2.6.1 V; 2.6.2 Nb; 2.6.3 Ta; 2.7 Group 6: Cr, Mo, W; 2.7.1 Cr; 2.7.2 Mo; 2.7.3 Tungsten; 2.8 Group 7: Mn, Tc, Re; 2.8.1 Mn; 2.8.2 Tc. - 2.8.3 Re2.9 Group 8: Fe, Ru, Os; 2.9.1 Fe; 2.9.2 Ru; 2.9.3 Os; 2.10 Group 9: Co, Rh, Ir; 2.10.1 Co; 2.10.2 Rh; 2.10.3 Ir; 2.11 Group 10: Ni, Pd, Pt; 2.11.1 Ni; 2.11.2 Pd; 2.11.3 Pt; 2.12 Group 11: Cu, Ag, Au; 2.12.1 Cu; 2.11.2 Ag; 2.11.3 Au; 2.13 Group 12: Zn, Cd, Hg; 2.13.1 Zn; 2.13.2 Cd; 2.13.3 Hg; 2.14 Group 13: B, Al, Ga, In, Tl; 2.14.1 B; 2.14.2 Al; 2.14.3 Ga; 2.14.4 In; 2.14.5 Tl; 2.15 Group 14: C, Si, Ge, Sn, Pb; 2.15.1 C; 2.15.2 Si; 2.15.3 Ge; 2.15.4 Sn; 2.15.5 Pb; 2.16 Group 15: N, P, As, Sb, Bi; 2.16.1 P; 2.16.2 As; 2.16.3 Sb, Bi; 2.17 Lanthanides; 2.18 Actinides. - 3.2.1.13 TpMe-TpMe3.2.1.14 Tppy-Tppy; 3.2.2 3-Monosubstituted Ligands, TpR; 3.2.2.1 TpMe and pzoTpMe; 3.2.2.2 TpPerfluoroalkyl (TpCF3, TpC2F5, TpC3F7); 3.2.2.3 TpiPr, pzoTpiPr and TpiPr*; 3.2.2.4 TpCPr, pzoTpCpr (Cpr = cyclopropyl); 3.2.2.5 TptBu, pzoTptBu; 3.2.2.6 TpCbu, pzoTpCbu (Cbu = Cyclobutyl); 3.2.2.7 TpNp and TpNP* (Np = Neopentyl); 3.2.2.8 TpCpe and pzoTpCpe (Cpe = Cyclopentyl); 3.2.2.9 TpCy and pzoTpCy (Cy = Cyclohexyl); 3.2.2.10 TpTrip (Trip = Tripticyl); 3.2.2.11 TpMenth and TpMementh (162 and 163); 3.2.2.13 pzoTpCamph (166); 3.2.2.14 TpPh, pzoTpPh and TpPh*. - 3.2.2.15 TpTol and pzoTpTol (Tol = p-Tolyl). - Chapter 3 Homoscorpionates - Second Generation3.1 General Considerations; 3.1.1 Regiochemistry in Ligand Synthesis; 3.1.2 The Quantification of Steric Effects in Tpx Ligands; 3.1.3 Ligand Rearrangments; 3.2 Individual Ligands; 3.2.1 B-Substituted Ligands, RTpx (R ≠ pzx); 3.2.1.1 MeTp; 3.2.1.2 EtTp; 3.2.1.3 iPrTp; 3.2.1.4 BuTp; 3.2.1.5 MeS(CH2)3Tp and MeS(CH2)3TpR; 3.2.1.5 MeS(CH2)3Tp and MeS(CH2)3TpR; 3.2.1.6 PhTp and PhTptBu; 3.2.1.7 TolTp (mixture of m- and p-); 3.2.1.8 (p-BrPh)Tp; 3.2.1.9 (C6D5)Tp; 3.2.1.10 FcTp, Fc(Tp)2, FcTpMe and FcTpph; 3.2.1.11 Me2NTp; 3.2.1.12 Tp-Tp. - This book deals with polypyrazolylborates (scorpionates), a class of ligands known since 1966, but becoming rapidly popular with inorganic, organometallic and coordination chemists since 1986, because of their versatility and user-friendliness. They can be readily modified sterically and electronically through appropriate substitution on the pyrazole ring and on boron, and have led to a number of firsts in coordination chemistry (first stable CuCO complex, first monomeric MgR complex, and many other such firsts). Their denticity can range from two to four, their "Bite" can be adjusted, and add
Emner
Sjanger
Dewey
ISBN
1860941729

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