Supercritical Water
Yizhak. Marcus
Bok Engelsk 2012 · Electronic books.
| Annen tittel | |
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| Utgitt | Hoboken : : Wiley, , 2012.
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| Omfang | 1 online resource (220 p.)
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| Utgave | 2nd ed.
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| Opplysninger | Description based upon print version of record.. - SUPERCRITICAL WATER: A Green Solvent: Properties and Uses; Contents; Preface; List of Acronyms and Symbols; 1 Introduction; 1.1 Phase Diagrams of Single Fluids; 1.2 The Critical Point; 1.3 Supercritical Fluids as Solvents; 1.4 Gaseous and Liquid Water; 1.5 Near-Critical Water; 1.6 Summary; References; 2 Bulk Properties of SCW; 2.1 Equations of State(EoS); 2.1.1 PVT Data for SCW; 2.1.2 Classical Equations of State of SCW; 2.1.3 Scaling Equations of State for SCW; 2.1.4 EoS of Supercritical Heavy Water; 2.2 Thermophysical Properties of SCW; 2.2.1 Heat Capacity; 2.2.2 Enthalpy and Entropy. - 2.2.3 Sound Velocity2.3 Electrical and Optical Properties; 2.3.1 Static Relative Permittivity; 2.3.2 Electrical Conductivity; 2.3.3 Light Refraction; 2.4 Transport Properties; 2.4.1 Viscosity; 2.4.2 Self-Diffusion; 2.4.3 Thermal Conductivity; 2.5 Ionic Dissociation of SCW; 2.6 Properties Related to the Solvent Power of SCW; 2.7 Summary; References; 3 Molecular Properties of SCW; 3.1 Diffraction Studies of SCW Structure; 3.1.1 X-Ray Diffraction Studies of SCW Structure; 3.1.2 Neutron Diffraction Studies of SCW Structure; 3.2 Computer Simulations of SCW; 3.2.1 Monte Carlo Simulations. - 3.2.2 Molecular Dynamics Simulations3.3 Spectroscopic Studies of SCW; 3.3.1 Infrared Absorption Spectroscopy; 3.3.2 Raman Scattering Spectroscopy; 3.3.3 Nuclear Magnetic Resonance; 3.3.4 Dielectric Relaxation Spectroscopy; 3.4 The Extent of Hydrogen Bonding in SCW; 3.5 The Dynamics of Water Molecules in SCW; 3.6 Summary; References; 4 SCW as a "Green" Solvent; 4.1 Solutions of Gases in SCW; 4.1.1 Phase Equilibria; 4.1.2 Interactions in the Solutions; 4.2 Solutions of Organic Substances in SCW; 4.2.1 Phase Equilibria; 4.2.2 Interactions in the Solutions; 4.3 Solutions of Salts and Ions in SCW. - 4.3.1 Solubilities of Salts and Electrolytes4.3.2 Thermodynamic Properties; 4.3.3 Transport Properties; 4.3.4 Ion Association in SCW; 4.3.5 Ion Hydration in SCW; 4.4 Binary Mixtures of Cosolvents with SCW; 4.5 Summary; References; 5 Applications of SCW; 5.1 Conversion of Organic Substances to Fuel; 5.1.1 Conversion to Hydrogen and Natural Gas; 5.1.2 Conversion to Liquid Fuel; 5.2 Supercritical Water Oxidation; 5.2.1 General Aspects of SCWO Process; 5.2.2 Examples of SCWO Applications; 5.3 Uses of SCW in Organic Synthesis; 5.4 Uses in Powder Technology of Inorganic Substances. - 5.5 Geothermal Aspects of SCW5.6 Application of SCW in Nuclear Reactors; 5.7 Corrosion Problems with SCW; 5.8 Summary; References; Author Index; Subject Index. - Discover the many new and emerging applications of supercritical water as a green solvent Drawing from thousands of original research articles, this book reviews and summarizes what is currently known about the properties and uses of supercritical water. In particular, it focuses on new and emerging applications of supercritical water as a green solvent, including the catalytic conversion of biomass into fuels and the oxidation of hazardous materials. Supercritical Water begins with an introduction that defines supercritical fluids in general. It then defines supercritical wa
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| Emner | |
| Sjanger | |
| Dewey | |
| ISBN | 9780470889473
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