On Being Well-Coordinated : A Half-Century of Research on Transition Metal Complexes
Fred. Basolo
Bok Engelsk 2003 · Electronic books.
| Annen tittel | |
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| Utgitt | Singapore : : World Scientific Publishing Company, , 2003.
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| Omfang | 1 online resource (654 p.)
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| Opplysninger | Description based upon print version of record.. - Contents; Preface; PART I Coordination Chemistry; 1. Ligand substitution reactions of transition metal complexes; 1.1. Base hydrolysis of [Co(NH3)5Cl]2+; 1.2. Ligand substitution reactions of other octahedral metal complexes; 2. Application of reaction mechanisms to the synthesis of metal complexes; 2.1. Synthesis of linkage isomers; 2.2. Synthesis of Pt(IV) compounds; 2.3. Isolation of solid compounds; 2.4. Concepts of bonding used in syntheses design; 3. Mechanisms of racemization of metal complexes; 3.1. Stereochemical changes during ligand substitution. - 3.2. Racemization of metal complexes4. Ligand substitution reactions of square planar metal coordination complexes; 4.1. Pioneers of Pt(II) chemistry; 4.2. Modern Pt(II) chemistry; 4.3. Nucleophilic reactivity constants, n0Pt; 5. References and reprints of Part I publications; DISSOCIATION MECHANISM FOR THE AQUATION OF SOME COBALT(III) COMPLEX IONS; Mechanism of Substitution Reactions in Complex Ions. II. Stereochemical Changes Accompanying Some Reactions of Cobalt(III) Complexes; Experimental; Discussion. - Deuterium Isotope Effect on the Aquation and Hydrolysis Rates of Aqueous [Co(NH3 )5CL]+2 and [Co(NH3)5Br]+2EXPERIMENTAL PROCEDURES; EXPERIMENTAL RESULTS; DISCUSSION; REFERENCES; Mechanism of Substitution Reactions in Complex Ions. VII. Base Hydrolysis of Some Cobalt(III) Complex Ions; Experimental; Results and Discussion; Synthesis and Properties of Some Fluoro-bis-(ethylenedianiine)-cobalt(III) Complexes; Experimental; Discussion; Acknowledgment. - Mechanism of Racemization of Complex Ions. I. Kinetics of the Dissociation and Racemization of Tris-(1,10-phenanthroline)-nickel(II) and Tris-(2,2'-dipyridyl)nickel (II) ComplexesExperimental; Results; Mechanism of Racemization of Complex Ions. II. Kinetics of the Dissociation and Racemization of Tris-(1,10-phenanthroline)-iron(II) and Tris-(2,2'-dipyridyl)-iron(II) Complexes; Experimental; Results and Discussion; Mechanism of Substitution Reactions of Complex Ions. VI. Formation of Nitrito- and Nitrocobalt(III) Complexes. O-Nitrosation; Experimental; Discussion. - Mechanism of Substitution Reactions of Complex Ions. IX. Contribution of Inductive Effects to the Rates of Acid and Base Hydrolysis of Cobalt(III) ComplexesExperimental; Results and Discussion; Mechanism of Substitution Reactions of Complex Ions. X. n-Bonding in Dissociation Reactions of Octahedral Complexes; Mechanism of Substitution Reactions in Complex Ions. XI. Rates of Hydrolysis and Racemization of Difluoro-bis-(ethylenediamine)-cobalt(III); Experimental; Results and Discussion. - Mechanism of Substitution Reactions of Complex Ions. XII. Reactions of Some Platinum(II) Complexes with Various Reactants. - This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended struct
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| Emner | |
| Sjanger | |
| Dewey | |
| ISBN | 9812380876
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