Synthetic Coordination Chemistry : Principles and Practice
Julian. Davies
Bok Engelsk 1996 · Electronic books.
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| Utgitt | Singapore : : World Scientific Publishing Company, , 1996.
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| Omfang | 1 online resource (472 p.)
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| Opplysninger | Description based upon print version of record.. - ACKNOWLEDGMENTS; PREFACE; DEDICATION; LIST OF ABBREVIATIONS; CONTENTS; Chapter 1. SYNTHESIS OF COORDINATION COMPOUNDS: THEORETICAL CONSIDERATIONS; 1.1 Labile and inert coordination compounds; 1.2 Synthesis of mixed-ligand complexes by co-proportionation; 1.3 The chelate effect; 1.4 The trans-effect; 1.5 The cis-effect; 1.6 Geometric isomerization of square-planar platinum(II) and palladium(II) complexes; 1.7 The effective atomic number concept; 1.8 The 16-/18-electron rule; 1.9 The hard-soft acid-base (HSAB) principle; 1.10 Factors affecting the acid/base properties of coordination compounds. - 1.11 Ligand effects on redox potentials of coordination compounds1.12 Reactivity of coordinated ligands; References; Chapter 2. THE SOLUBILITY OF COORDINATION COMPOUNDS: RELATIONSHIP TO COMPOSITION AND STRUCTURE; 2.1 Hydrophilic and lipophilic coordinated ligands; 2.2 Solubility of ionic complexes: counterion effects; 2.3 Changes in solubility through modification of cationic counterions; 2.4 Solubility of complexes in mixed solvents; References; Chapter 3. GENERATION OF SOLVENTO-COMPLEXES; 3.1 Halide abstraction reactions. - 3.2 Solvento-complexes from redox transformations of coordination compounds3.2.1 Redox transformations of N-donor ligands; 3.2.2 Redox transformations with other classes of ligands; 3.2.3 Oxidation or reduction of central atoms; 3.3 Formation of solvento-complexes through reactions of coordinated ligands (non-redox); 3.4 Dehydration reactions of aqua-complexes and formation of solvento-complexes; 3.5 Decarbonylation reactions and removal of other supporting ligands (olefins, acetylenes, arenes, dinitrogen). - 3.6 Application of solvento-complexes in the synthesis of bridged hetero- and homopolynuclear complexes3.7 Complexes containing coordinated halocarbons; References; Chapter 4. HOMOLEPTIC SOLVENTO-COMPLEXES: STARTING MATERIALS FOR PREPARATIVE COORDINATION CHEMISTRY; 4.1 Introduction; 4.2 Synthesis of solvento-complexes by metal oxidation in non-aqueous solvents; 4.3 Synthesis of solvento-complexes by dissolution of salts in non-aqueous solvents; 4.4 Synthesis of solvento-complexes by dehydration of aqua-complexes and hydrated salts. - 4.5 Synthesis of solvento-complexes by substitution of ligated solvent molecules4.6 Synthesis of solvento-complexes by halide abstraction from salts and complexes; References; Chapter 5. SYNTHESIS VIA ION EXCHANGE IN NON-AQUEOUS SOLVENTS; 5.1 Ligand substitution by ion exchange in non-aqueous solvents; 5.2 Synthesis of complexes containing classically ""noncoordinating"" anions as ligands; 5.3 Formation of chelate complexes by ion exchange in non-aqueous solvents; 5.4 Synthesis of complexes containing metal-metal bonds between transition metals. - 5.5 Synthesis of complexes containing transition metal-main group metal/metalloid bonds. - Although coordination chemistry naturally centers on the synthesis of coordination compounds, the synthesis of these materials is typically not an end in itself. Coordination compounds are utilized in all branches of chemistry; from theoretical modeling to industrial and consumer products. While a large amount of information is available on coordination chemistry in general and synthetic methods in particular, no comprehensive work has been presented on the preparation of coordination compounds with an emphasis on synthetic strategies rather than on detailed descriptions of specific syntheses.
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| Emner | Coordination compounds - Synthesis
Chemistry Physical & Theoretical Chemistry Physical Sciences & Mathematics koordinasjonsforbindelser kompleksforbindelser |
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| ISBN | 9810220847
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