Distinctive Techniques for Organic Synthesis


Tse-Lok. Ho
Bok Engelsk 1998 · Electronic books.
Annen tittel
Medvirkende
Ho, Tse-Lok. (Author)
Utgitt
Singapore : : World Scientific Publishing Company, , 1998.
Omfang
1 online resource (400 p.)
Opplysninger
Description based upon print version of record.. - Contents; Preface; General Abbreviations; 1. Phase Transfer Reactions; 1.1. Substitutions; 1.1.1. With Cyanide Ion; 1.1.2. With Halide Ions; 1.1.3. With Oxide Anions; 1.1.4. With Other Nucleophiles; 1.2. Alkylations; 1.3. Condensations; 1.4. Eliminations and Additions; 1.4.1. B-Eliminations; 1.4.2. a-Eliminations; 1.4.3. Addition Reactions; 1.5. Oxidations; 1.5.1. Oxidation of Alkenes Alkynes and Arenes; 1.5.2. Oxidation of Heterofunctional Compounds; 1.6. Reductions; Monographs and Reviews; References; 2. Reactions with Solid-supported Reagents and Catalysts; 2.1. Polymer-based Supports. - 2.1.1. Preparation of Functionalized Polymers by Copolymerization2.1.2. Chemical Modification of Polymers; 2.1.3. Reactions with Polymer-supported Reagents; 2.1.4. Polymeric Protecting Groups; 2.1.5. Reactions with Polymer-supported Catalysts; 2.2. Inorganic Supports; 2.2.1. Acid- and Base-catalyzed Reactions; 2.2.2. Substitutions; 2.2.3. Halogenation; 2.2.4. Cycloadditions; 2.2.5. Oxidations; 2.2.6. Reductions; Monographs and Reviews; References; 3. Sonochemistry; 3.1. Isomerizations; 3.2. Hydrolysis; 3.3. Oxidations; 3.4. Reduction Reductive Elimination and Coupling. - 3.5. Eliminations and Additions3.6. Condensations; 3.7. Cycloadditions; 3.8. Substitutions; 3.8.1.On Carbon; 3.8.2 On Heteroatoms; 3.9. Various Preparations; Monographs and Reviews; References; 4. High Pressure Reactions; 4.1. Substitution Reactions; 4.2. Additions; 4.2.1. Addition to the Carbonyl Group; 4.2.2. Addition to Alkenes; 4.3. Condensation Reactions; 4.4. Cycloadditions; 4.4.1. Diels-Alder Reactions; 4.4.2. Other Cycloadditions; Monographs and Reviews; References; 5. Flash Vacuum Pyrolysis and Some Other Thermal Processes; 5.1. Elimination Reactions; 5.1.1. a-Elimination. - 5.1.2. B-Elimination and Related Cycloreversions5.1.3. Remote Eliminations; 5.2. Cheletropic Extrusions and Other Ring Fissions; 5.3. Thermal Cleavage of Four-membered Rings; 5.4. Electrocyclic Reactions; 5.5. Retro-Diels-Alder Reactions; 5.6. The Ene Reaction and Its Reversion; 5.7. Rearrangements; 5.7.1. 1 2-Rearrangements; 5.7.2. Other Rearrangements; Monographs and Reviews; References; 6. Electroorganic Transformations; 6.1. Electrooxidation and Functionalization; 6.1.1. Of Hydrocarbons; 6.1.2. Of Aromatic Systems; 6.1.3. Of Heterocycles; 6.1.4. Of Heterofunctional Compounds. - 6.1.5. Of Anions6.2. Electroreduction; 6.2.1. Of CC Multiple Bonds; 6.2.2. Of C-X Bonds; 6.2.3. Reduction and Reductive Alkylation of X=Y Bonds; 6.3. Reactions with Electrochemically Generated Acids and Bases; Monographs and Reviews; References; 7. Organic Photochemistry; 7.1. General Considerations; 7.2. Cleavage and Recombination; 7.3. Cycloadditions; 7.3.1. [2+2]Cycloadditions; 7.3.2. Photocycloaddition of Arenes; 7.3.3. Other Photocycloadditions; 7.4. Photoisomerization of Alkenes and Arenes; 7.4.1. (E Z)-Isomerizations; 7.4.2. Electrocyclic Reactions; 7.5. Rearrangements. - 7.5.1. Of Conjugated Ketones. - This important book is intended to familiarize the practitioner of synthetic chemistry with somewhat extraordinary techniques which should prove very helpful to his or her work. It covers some reactions or techniques for organic synthesis which are not found in most introductory texts. They include reactions under high pressure, mediated by ultrasonic, flash vacuum pyrolysis, photochemical processes, phase transfer reactions, electrochemical reactions, and reactions on solid supports. The emphasis of the book is on applications. Examples are often drawn from significant contributions, such as
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Sjanger
Dewey
ISBN
9810232527

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