Integrated Approach to Coordination Chemistry : An Inorganic Laboratory Guide
Rosemary A. Marusak
Bok Engelsk 2007 · Electronic books.
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| Utgitt | Hoboken : : Wiley, , 2007.
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| Omfang | 1 online resource (290 p.)
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| Opplysninger | Description based upon print version of record.. - INTEGRATED APPROACH TO COORDINATION CHEMISTRY; CONTENTS; Acknowledgments; 1. Experimental Inorganic Chemistry: A History of Dazzling Color!; Early Developments in Inorganic Chemistry; Complex Ions; On the Nature of the Coordinate Bond-Bonding Models; Valence Bond Theory; Crystal Field Theory; Molecular Orbital Theory and Ligand Field Theory; Origin of Color in Transition Metal Coordination Complexes; Coordination Complex Reactivity; Substitution Reactions; Electron Transfer Reactions; Applications of Coordination Complexes; Aspects of Inorganic Synthesis-Governing Factors. - 3. Levels 3 and 4. Molecular Geometry and Stability: Solid and Solution Phase Analysis of N,N'-disalicylaldehyde-1,3-propanediimine nickel(II). - Experiment 2.5: Analysis of Cobalt Coordination Compounds III: Potentiometric Analysis of Ionic Halide (Chloride/Bromide)Level 2; Pre-lab 2.5; Procedure 2.5; Experiment 2.6: Analysis of Cobalt Coordination Compounds IV-Determination of Equivalent Weight by Ion Exchange Chromatography; Level 2; Pre-lab Questions; Pre-lab 2.6; Procedure 2.6: Preparation of the Cation Exchange Column; Post-lab Question; Experiment 2.7: Confirming Your Analysis-Visible Spectroscopy of Cobalt Ammine Complexes; Level 2; Procedure 2.7; References. - Pre-lab QuestionsProcedure 2.2.a: Synthesis of Cobalt Complex I; Procedure 2.2.b: Synthesis of Cobalt Complex II; Procedure 2.2.c: Synthesis of Cobalt Complex III; Post-lab Questions; Experiment 2.3: Analysis of Cobalt Coordination Compounds I: Spectrophotometric Determination of Cobalt; Level 1; Pre-lab Questions; Pre-lab 2.3.a Introduction to Visible Spectroscopy and Beer's Law(15); Pre-lab 2.3.b: Weighing by Difference; Pre-lab 2.3.c: Visible Spectroscopy of the Hexaaquacobalt(II) Ion; Procedure 2.3.a: Preparation of Co(2+)(aq) Standard Solutions. - Procedure 2.3.b: Preparation of the Cobalt Coordination Compound Sample Solution-Decomposition and Reduction of Cobalt(III) to Cobalt(II).Procedure 2.3.c: Measurement of the Visible Spectrum of the Aquated Co(II) Ion: [Co(H(2)O)(6)](2+); Procedure 2.3.d: Preparation of Beer's Law Calibration Plot and Sample Analysis; Post-lab Questions; Experiment 2.4: Analysis of Cobalt Coordination Compounds II-Acid-Base Titrimetric Determination of Ammonia; Level 2; Pre-lab Questions; Pre-lab 2.4.a: Acid-Base Titrations of Solutions Containing Two Acids; Procedure 2.4. - Synthesis: An Interplay Between Thermodynamics and KineticsAcid-Base Chemistry (Hard-Soft-Acid-Base Theory); Stoichiometry; The Art of Precipitation: Properties of Precipitates; References; 2. Levels 1-2. Werner's Notion-Creating the Field: Synthesis and Analysis of Cobalt Ammine Coordination Compounds; Project Overview; Experiment 2.1: Exploring the Werner-Jørgensen Debate on Metal Complex Structure; Level 1; Jørgensen's Chain Theory; Werner's Coordination Theory; Testing the Theories; Werner's Triumph!; Experiment 2.2: Synthesis of a Cobalt Ammine Coordination Compound; Level 1. - Coordination chemistry is the study of compounds formed between metal ions and other neutral or negatively charged molecules. This book offers a series of investigative inorganic laboratories approached through systematic coordination chemistry. It not only highlights the key fundamental components of the coordination chemistry field, it also exemplifies the historical development of concepts in the field. In order to graduate as a chemistry major that fills the requirements of the American Chemical Society, a student needs to take a laboratory course in inorganic chemistry. Most professor
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| ISBN | 047146483X. - 9780471464839
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