Esterification : Methods, Reactions, and Applications
Junzo. Otera
Bok Engelsk 2009 · Electronic books.
| Annen tittel | |
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| Utgitt | Hoboken : : Wiley, , 2009.
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| Omfang | 1 online resource (388 p.)
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| Utgave | 2nd ed.
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| Opplysninger | Description based upon print version of record.. - Esterification; Contents; Preface; Preface to the Second Edition; Introduction; Part One: Methodology; 1: Reaction of Alcohols with Carboxylic Acids and their Derivatives; 1.1 Reaction with Carboxylic Acids; 1.1.1 Without Activator; 1.1.2 Acid Catalysts; 1.1.2.1 Brønsted Acids; 1.1.2.2 Lewis Acids; 1.1.2.3 Solid Acids; 1.1.3 Base Activators; 1.1.4 Carbodiimide Activators; 1.1.5 The Mitsunobu Reaction; 1.1.6 Activation of Carboxylic Acids; 1.1.7 Enzymes; 1.1.8 π-Acids; 1.2 Reaction with Esters: Transesterification; 1.2.1 Without Activator; 1.2.2 Acid Catalysts; 1.2.2.1 Brønsted Acids. - 1.2.2.2 Lewis Acids1.2.2.3 Solid Acids; 1.2.3 Base Activators; 1.2.3.1 Metal Salts; 1.2.3.2 Amines; 1.2.3.3 Others; 1.2.4 Other Activators; 1.2.5 Enzymes; 1.3 Reaction with Acid Anhydrides; 1.3.1 Without Activator; 1.3.2 Acid Catalysts; 1.3.2.1 Brønsted Acids; 1.3.2.2 Lewis Acids; 1.3.2.3 Solid Acids; 1.3.3 Base Activators; 1.3.3.1 Metal Salts; 1.3.3.2 Amines; 1.3.3.3 Phosphines; 1.3.4 Enzymes; 1.3.5 Mixed Anhydrides; 1.4 Reaction with Acid Halides and Other Acyl Derivatives; 1.4.1 Without Activator; 1.4.2 Acid Catalysts; 1.4.2.1 Bønsted Acids; 1.4.2.2 Lewis Acids; 1.4.2.3 Solid Acids. - 1.4.3 Base Activators1.4.3.1 Metal Salts; 1.4.3.2 Amines; 1.4.3.3 Phase Transfer Catalyst; 1.4.4 Other Activators; 1.4.5 Enzymes; 2: Use of Tin and Other Metal Alkoxides; 3: Conversion of Carboxylic Acids into Esters without Use of Alcohols; 3.1 Reaction with Diazomethane; 3.2 Reaction with Alkyl Halides; 3.3 Treatment with Other Electrophiles; 4: Ester Interchange Reaction; Part Two: Synthetic Applications; 5: Kinetic Resolution; 5.1 Enzymatic Resolution; 5.2 Nonenzymatic Resolution; 5.3 Dynamic Kinetic Resolution; 5.4 Parallel Kinetic Resolution; 6: Asymmetric Desymmetrization. - 7: Miscellaneous Topics7.1 Selective Esterification; 7.1.1 Differentiation between Primary, Secondary, and Tertiary Alcohols, and Phenols; 7.1.2 Differentiation between Identical or Similar Functions; 7.2 Use of Theoretical Amounts of Reactants; 7.3 New Reaction Media; 7.4 New Technologies; 7.5 Application to Natural Products Synthesis; 8: Industrial Uses; 8.1 Ethyl Acetate; 8.2 Acrylic Esters; 8.2.1 Methyl Methacrylate (MMA); 8.2.2 Alkyl Acrylates; 8.3 Polyesters; 8.4 Oils and Fats; 8.4.1 Food Emulsifiers; 8.4.2 Soaps; 8.5 Biodiesel Fuel; 8.6 Amino Acid Esters; 8.7 Macrolides. - 8.8 Flavoring Agents and Fragrances8.9 Pyrethroids; Epilogue; References; Index. - Gathering together the widespread literature in the field, this monograph acts as a reference guide to this very important chemical reaction. Following an introduction, the book goes on to discuss methodology, before treating synthetic and industrial applications -- the latter being a new focus in this completely revised, updated and extended second edition. A must-have for organic, natural products and catalytic chemists, as well as those working in industry, of for lecturers in chemistry.
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| Emner | |
| Sjanger | |
| Dewey | |
| ISBN | 9783527322893
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